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Introduction  
Sn-Pb Properties and Models  
Sn-Ag Properties and Creep Data  
Sn-Ag-Cu Properties and Creep Data  
General Conclusions/ Recommendations  
Acknowledgements  
References  
     
  For more information contact:  
  metallurgy@nist.gov  
 
Sn-Ag Properties and Creep Data
 
  Overview and Conclusions  
  Bulk Sn-3.5Ag Tensile Creep  
  Source and Plot of Data  
  Specimens  
  Microstructures  
  Data Analysis  
  Discussion  
  Comparison to Sn-4Ag Tensile Creep Data  
  Sn-3.5Ag Compression Creep  
  Raw Data  
  Data Analysis  
  Comparison of Tensile and Compressive Creep  
  Creep of Sn-3.5Ag Lap Shear and Plug & Ring Joints  
  Shear Joint Sizes  
  Sn-3.5Ag Lap Joint and Plug & Ring Shear Data  
  Analysis of Sn-3.5Ag Lap Joint and Plug & Ring Shear Data  
  Comparison to Sn-3.65Ag and Sn-4Ag Data  
  Creep of Sn-3.5Ag CCC Solder Joints in Shear  
  Darveaux's Sn-3.5Ag Data  
  Fit of Darveaux's Data to Lap Shear and Plug & Ring Correlation Band  
  Regression of Darveaux's CCC Shear Data  
  Creep of Sn-3.5Ag Flip-Chip Solder Joints in Shear  
  Flip-Chip Sn-3.5Ag Shear Data  
  Comparison of Flip-Chip and CCC Solder Joint Shear Data  
  Other Properties of Sn-3.5Ag  
  Young's Modulus vs. Temperature  
  Poisson's Ratio  
  Coefficients of Thermal Expansion (CTE)  
  Other Physical Properties  
  Discussion  
  Data Scatter  
  Multiaxial Conditions  
  Constitutive Modeling  
  Recommendations  
 

Sn-3.5Ag Compression Creep

Raw Data

Figure 11: Bulk Sn-3.5Ag compression creep data.

Figure 11: Bulk Sn-3.5Ag compression creep data.


NCMS conducted isothermal load-controlled, compression creep tests on cylindrical specimens 0.4" (10.16 mm) in diameter by 0.8" (20.32mm) in length. Prior to chill-casting the specimens, Sn-3.5Ag solder was heated up 40°C above its melting point (221°C). Tests were conducted at 20°C, 75°C and 125°C. The raw data is listed in Table A.3 and is plotted in Figure 11.

Data Analysis

Figure 12: Power-law fit to bulk Sn-3.5Ag compression creep data.

Figure 12: Power-law fit to bulk Sn-3.5Ag compression creep data.

We were not able to fit the compression data to a hyperbolic sine model, thus the data was fit to a simpler power law model:

Equation 29 (29)
special definitions:
  A, n, Q fitting constants as previously defined  

 

The analysis was done on Y=ln(epsilon degree) with the regression function specified as:

Equation 30 (30)

where LNA = ln(A) and Qa = Q/R. The regression results from the "Datafit" program are given as central values with standard deviations:

  • LNA = -9.268 ± 2.081 (from which the central value of A is: A = 9.44e-5)
  • n = 6.05 ± 0.70
  • Qa = 7349 ± 753 (from which the central value of Q is: Q = 61.1 kJ/mole ~ 0.63 eV)

The best fit line in Figure 12 is thus plotted from the master curve equation:

Equation 31 (31)

 

Comparison of Tensile and Compressive Creep

Figure 13: Sn-3.5Ag compression creep data compared to master curve of tensile creep data.

Figure 13: Sn-3.5Ag compression creep data compared to master curve of tensile creep data.

Figure 13 shows the NCMS compression creep data compared to the plot of the master curve for the tensile creep data (Figure 9). Although the master curve is an approximate fit through the tensile data, Figure 13 clearly shows that Sn-3.5Ag is stronger in compression than in tension. The red curve in Figure 13 is also an approximate fit through the compressive data points and is 1.4 times to the right of the centerline for the tensile data.

Thus, Sn-3.5Ag behaves like an uneven material with higher strength or more creep resistance in compression than in tension. It is important to keep this uneven behavior in mind, especially when conducting finite element analysis. Finite element modeling of Sn-3.5Ag solder joints should be done with a finite element code that can handle compressive and tensile creep constitutive equations separately.


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